It is generally recommended to have the house rendering done first, and then have the UPVC windows sprayed afterwards.
This is because rendering is typically a messy process, involving the application of wet plaster or other materials to the exterior of the house. If the windows were sprayed first, there is a risk that the rendering process could damage or stain the freshly painted surfaces, leading to additional cleanup or touch-up work.
By completing the rendering first, you can ensure that the window frames are protected during the messy work, and that the newly sprayed surfaces are not at risk of damage. Once the rendering is complete and has had a chance to dry, you can then schedule the UPVC window spraying to achieve a smooth, clean finish.
Of course, it's always a good idea to consult with your contractor to confirm the best order of operations for your specific project, as there may be unique factors to consider in your situation.