Most buildings built before 1920 were typically built using lime mortar. Unfortunately once a building has been repointed in sand and cement, it is very difficult to remove without damaging the stone or brickwork.
If you're lucky, it was repointed using a weak cement mix (6:1) and can be safely removed. If not, then there isn't much you can do except angle grinder the mortar back out. This method is far from ideal.
Depending on the age and condition of the masonary of your building, different types of lime and lime mixes can be used. NHL lime has been the "go to" product for a while now but is increasingly becoming less popular as they cure very hard which can also damage masonary work. Hot and fat limes are becoming recognised as the correct product to use.
Try to think of the lime mortar joint as being the perishable part of exterior of your building. It will absorb most of the moisture qhile also allowing it to evaporate. It will also perish before any bricks and stone hence the saying "perishable part".
UNDER NO CIRCUMSTANCES SHOULD CEMENTOUS PRODUCTS OR MIXES IN ANY AMOUNT BE USED ON PERIOD BUILDINGS!!!!!